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Toxic and Hazardous Substances (including Hazardous Materials)
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General Industry. This topic covers hazardous substances regulated under OSHA’s toxic and hazardous substances rules, such as acetylene, benzene, hexavalent chromium, vinyl chloride, and other substances under 1910.1002 to 1910.1096 not covered by their own topics (e.g., asbestos and lead) and not air contaminants (mold, silica, etc.). You’ll also find information here about storage and handling of OSHA hazardous materials such as liquefied petroleum gases and storage and handling of anhydrous ammonia. There is also training material for hazardous waste regulated under EPA.

Construction Industry. Toxic and hazardous substances in construction are regulated under 29 CFR 1926.55 (gases, vapors, fumes, dusts, and mists) and 29 CFR 1926 Subpart Z (toxic and hazardous substances). With the exception of stricter or more detailed construction requirements for asbestos, cadmium, and hexavalent chromium, the requirements of 1926 Subpart Z are an adoption of the general industry regulations under 1910 Subpart Z. The construction permissible exposure limits (PELs) for hazardous substances (29 CFR 1926.55, Appendix A) generally mirror the general industry PELs, except the construction PELs for certain hazardous dusts are stricter than the general industry PELs.

For related resources and training materials, refer to the following topics:

For information on DOT Hazardous Materials (HazMat) regulations, refer to the following topics:

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Interpretations Access to employee exposure and medical records. 10/29/1997National
Interpretations PVC used in window frames and siding. 02/25/1997National
Directives 01/24/2008 - CPL 02-02-074 - Inspection Procedures for the Chromium (VI) Standards 01/24/2008National
Directives 01/24/2008 - CPL 03-00-007 - National Emphasis Program--Crystalline Silica 01/24/2008National
Directives 06/22/1992 - CPL 2-2.42 - Guidelines for Implementing the Field Sanitation Standard 07/22/2003National
7 Minute Safety Trainer 1,3-Butadiene  National
Handouts 1,3-Butadiene  National
Quizzes 1,3-Butadiene  National
Handouts 1,3-Butadiene [7-Minute Safety Trainer] - Spanish  National
Quizzes 1,3-Butadiene [7-Minute Safety Trainer] - Spanish  National
Directives 10/30/1978 - STD 1-5.4 - Application of Section 1910.106, Flammable and Combustible Liquids and Particulary Diking Requirements of ... 07/08/2003National
Regulations 29 CFR § 1910.1002 Coal tar pitch volatiles; interpretation of term  National
Regulations 29 CFR § 1910.1003 13 Carcinogens (4-Nitrobiphenyl, etc.)  National
Regulations 29 CFR § 1910.1004 alpha-Naphthylamine  National
Regulations 29 CFR § 1910.1006 Methyl chloromethyl ether  National
Regulations 29 CFR § 1910.1007 3,3'-Dichlorobenzidine (and its salts)  National
Regulations 29 CFR § 1910.1008 bis-Chloromethyl ether  National
Regulations 29 CFR § 1910.1009 beta-Naphthylamine  National
Regulations 29 CFR § 1910.1010 Benzidine  National
Regulations 29 CFR § 1910.1011 4-Aminodiphenyl  National
Regulations 29 CFR § 1910.1012 Ethyleneimine  National
Regulations 29 CFR § 1910.1013 beta-Propiolactone  National
Regulations 29 CFR § 1910.1014 2-Acetylaminofluorene  National
Regulations 29 CFR § 1910.1015 4-Dimethylaminoazobenzene  National
Regulations 29 CFR § 1910.1016 N-Nitrosodimethylamine  National
Regulations 29 CFR § 1910.1017 Vinyl chloride  National
Regulations 29 CFR § 1910.1018 Inorganic arsenic  National
Regulations 29 CFR § 1910.102 Acetylene  National
Regulations 29 CFR § 1910.1026 Chromium (VI)  National
Regulations 29 CFR § 1910.1027 Cadmium.  National
Regulations 29 CFR § 1910.1028 Benzene  National
Regulations 29 CFR § 1910.1029 Coke oven emissions  National
Regulations 29 CFR § 1910.1043 Cotton dust  National
Regulations 29 CFR § 1910.1044 1,2-dibromo-3-chloropropane  National
Regulations 29 CFR § 1910.1045 Acrylonitrile  National
Regulations 29 CFR § 1910.1047 Ethylene oxide  National
Regulations 29 CFR § 1910.1048 Formaldehyde  National
Regulations 29 CFR § 1910.1096 Ionizing radiation  National
Regulations 29 CFR § 1910.97 Nonionizing radiation  National
Final Rules 29 CFR 1910 - Revising the Beryllium Standard for General Industry; Final Rule 07/14/2020National
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